Journal of Health Sciences & Surveillance System

Current Issue

By Issue

By Author

By Subject

Author Index

Keyword Index

About Journal

Aims and Scope

Editorial Board

Publication Ethics

Indexing and Abstracting

Related Links

FAQ

Peer Review Process

News

Catalytic oxidation of carbon monoxide from vented gas space heaters using alumina foam supported CuMnOx Nanocatalyst

Document Type : Original Article

Authors

1 Department of Environmental Health Engineering, School of Health, Student research committee, Shiraz University of Medical Sciences, Shiraz, Iran

2 Department of occupational health engineering, Shiraz university of medical science, Iran

3 Research Center for Health Sciences, Institute of Health, Department of Environmental Health, School of Health, Shiraz University of Medical Sciences, Shiraz, Iran-

Abstract

Introduction: Carbon monoxide (CO) is an odorless, tasteless, colorless, and nonirritating poisonous gas, recognized as the silent killer for the 21st century. It is produced during partial combustion of carbon-containing compounds. Improper ventilation and flue installation of vented gas space heaters cause carbon monoxide gas to penetrate the building, leading to many deaths annually. The catalytic oxidation of CO has received great attention due to its applications in different fields. In this study, alumina foam coated by CuMnOx catalyst was used to remove CO from the vented gas space heaters.
Method: This is a full-scale experimental study on the outflow from vented gas space heaters. Alumina foam supported hopcalite (CuMnOx) catalyst was synthesized using a co-precipitation method for CO oxidation from THE vented gas space heaters. The XRD and SEM were used to characterize the synthesized catalyst. The concentration of CO was measured by IMR 1500 combustion gas analyzer.
Result:  The particle size of the catalyst was in the range of 200-600 nm. XRD showed different crystallizations, and the crystal size was in the range of 20 -120 nm.  There was no significant CO removal in the case of using uncoated alumina foam. Results showed CuMnOx catalyst significantly increased the CO removal. The removal efficiencies were 83% and 89% in heating powers of 2300 and 3200 kcal/hr, respectively. The average CO conversation rate was approximately 60.45 µg/gr.min.
Conclusion: CuMnOx coated on alumina has a significant effect on CO removal from the vented gas space heaters. The catalyst and outlet gas temperature were the most important factors affecting CO removal. 

Keywords

References
1-      Singh, R. Prasad, Physico-chemical analysis and study of different parameters of hopcalite catalyst for CO oxidation at ambient temperature, Int. J. Sci. Eng. Res. 7 (4) (2016) 846–855
2-      2- X. Xie, Y. Li, Z. Liu, M. Haruta, W. Shen, Low-temperature oxidation of CO catalyzed by Co3O4 nanorods, Nature. 458 (2009) 746-749
3-      Dey S, Dhal GC, Mohan D, Prasad R, Gupta RN. Cobalt doped CuMnOx catalysts for the preferential oxidation of carbon monoxide. Applied Surface Science. 2018 May 31; 441:303-16.
4-      Dey S, Dhal GC, Mohan D, Prasad R. Synthesis of silver promoted CuMnOx catalyst for ambient temperature oxidation of carbon monoxide. Journal of Science: Advanced Materials and Devices. 2019;4(1):47-56.)
5-      D.V. Mahalakshmi, P. Sujatha, C.V. Naidu, V.M. Chowdary, Contribution of vehicular emissions on urban air quality: results from public strike in Hyderabad, Indian J. Radio Space Phys. 43 (2014) 340e348.
6-      Chaloulakou A, Mavroidis I, Duci A. Indoor and outdoor carbon monoxide concentration relationships at different microenvironments in the Athens area. Chemosphere. 2003;52(6):1007-19.
7-      Naddafi K, Rezaei S, Nabizadeh R, Younesian M, Jabbari H. Density of Airborne Bacteria in a Children Hospital in Tehran. Iranian Journal of Health and Environment. 2009;1(2):75-80.
8-      International Programme on Chemical Safety. Carbon monoxide. Geneva,
World Health Organization, 1999 (Environmental Health Criteria 213).
9-      Organization WH. WHO guidelines for indoor air quality: selected pollutants. 2010
10-  Hosseinpour s, Kashaniasl s. numerical and experimental investigation of baffles effect on thermal efficiency of room gas heater. 2010.
11-  http://www.lmo.ir/web_directory/54000%D9%85%D8%B3%D9%85%D9%88%D9%85%DB%8C%D8%AA-%D8%A8%D8%A7 %DA%AF%D8%A7%D8%B2.html
12-  Wang L, Yang L, Zhang Y, Ding W, Chen S, Fang W, Yang Y. Promoting effect of an aluminum emulsion on catalytic performance of Cu-based catalysts for methanol synthesis from syngas. Fuel Processing Technology. 2010 Jul 1; 91(7):723-8.
13-  Xanthopouloua G, Novikova V, Knysha YA, Amosova A. Nanocatalysts for Low-Temperature Oxidation of CO. Eurasian Chemico-Technological Journal. 2015;17(1):17-31.
14-  Faure R, Rossignol F, Chartier T, Bonhomme C, Maître A, Etchegoyen G, et al. Alumina foam catalyst supports for industrial steam reforming processes. Journal of the European Ceramic Society. 2011;31(3):303-12.
15-  Tabakova T, Kolentsova E, Dimitrov D, Ivanov K, Manzoli M, Venezia A, et al. CO and VOCs catalytic oxidation over alumina supported Cu–Mn catalysts: Effect of Au or Ag deposition. Topics in Catalysis. 2017;60(1-2):110-22.
16-   Ivanov KI, Kolentsova EN, Dimitrov DY, editors. Alumina Supported Coppermanganese Catalysts for Combustion of Exhaust Gases: Effect of Preparation Method. XIII International Conference on Chemical Engineering and Technology; 2015.
17-  Mobini S, Meshkani F, Rezaei M. Supported Mn catalysts and the role of different supports in the catalytic oxidation of carbon monoxide. Chemical Engineering Science. 2019;197:37-51.
18-  Jones CD. Ambient temperature oxidation of carbon monoxide by copper-manganese oxide based catalysts. Cardiff University; 2006.
19-  Lee J, Kim H, Lee H, Jang S, Chang JH. Highly efficient elimination of carbon monoxide with binary copper-manganese oxide contained ordered nanoporous silicas. Nanoscale research letters. 2016;11(1):6.
20-   Zhang H, Suszynski WJ, Agrawal KV, Tsapatsis M, Al Hashimi S, Francis LF. Coating of open cell foams. Industrial & Engineering Chemistry Research. 2012 Jun 29;51(27):9250-9.
21-  E.C. Njagi, C. Chen, H. Genuino, H. Galindo, H. Huang, S.L. Suib, Total oxidation of CO at ambient temperature using copper manganese oxide catalysts prepared by a redox method, Appl. Catal. A 99 (2010) 103–110
22-  Anh NT. Binary copper and manganese oxide nanoparticle supported oms-2 for enhancing activity and stability toward co oxidation reaction at low temperature. Vietnam Journal of Science and Technology. 2018 Dec 17;56(6):741.
23-  Dey S, Dhal GC, Prasad R, Mohan D. Effects of doping on the performance of CuMnOx catalyst for CO oxidation. Bulletin of Chemical Reaction Engineering & Catalysis. 2017 Oct 28;12(3):370-83.
Journal of Health Sciences & Surveillance System
Volume 7, Issue 2
April 2019
Pages 60-66
Files
Share
How to cite
Statistics