Khadijeh Darabi; Abooalfazl Azhdarpoor; Mansoureh Dehghani
Abstract
Background: Carbamazepine is a pharmaceutical compound used as an anticonvulsant for epilepsy and can enter the environment by inappropriate treatment of hospital wastewater. Therefore, the present study aimed to investigate the removal of carbamazepine from the aquatic environment, using the ozonation ...
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Background: Carbamazepine is a pharmaceutical compound used as an anticonvulsant for epilepsy and can enter the environment by inappropriate treatment of hospital wastewater. Therefore, the present study aimed to investigate the removal of carbamazepine from the aquatic environment, using the ozonation process. Methods: This is an experimental study in which certain concentrations of carbamazepine were removed, using the ozonation process. The effect of such factors as pH (3-11), carbamazepine concentration (5-15 ppm), ozone dose (200-400 mg/hr), and reaction time (15-180 seconds) on the removal efficiency was studied. Data analysis was performed to measure carbamazepine, using the High-Performance Liquid Chromatography (HPLC). Results: The results showed that the carbamazepine removal efficacy at pHs of 5, 7, and 11 was 81%, 66%, and 21%, respectively at 15 ppm, the reaction time of 30 seconds, and the ozone dose of 200 mg/hr, respectively. Also, at the dose of 200 and 400 mg/hr injectable ozone at pHs of 5 and 7, removal efficiency was 81%, 66%, 97%, and 78%, respectively. Conclusion: According to the results, at pH=5, reaction time of 30 seconds, the carbamazepine concentration of 15 ppm, injectable ozone dose of 200 mg/h, a removal efficiency of 81% was obtained. The ozonation process can react directly or indirectly with the drug contaminant in very low concentrations in aqueous solutions due to its high oxidation power, leading to its destruction or elimination, which may indicate that the ozonation method may be used as an effective method to remove carbamazepine and other similar contaminants.
Mohammad Ali Baghapour; Mohammad Reza Shirdarreh; Mohammad Faramarzian
Volume 2, Issue 1 , January 2014, , Pages 15-25
Abstract
Background: Amoxicillin is widely used as an antibiotic in the modern medicine. Due to its chemical structure, polarity, activity level, antibiotic specifications, and environmental sustainability, Amoxicillin leaks into the groundwater, surface waters, and drinking water wells. Many physical and chemical ...
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Background: Amoxicillin is widely used as an antibiotic in the modern medicine. Due to its chemical structure, polarity, activity level, antibiotic specifications, and environmental sustainability, Amoxicillin leaks into the groundwater, surface waters, and drinking water wells. Many physical and chemical methods have been suggested for removing Amoxicillin from aquatic environments. However, these methods are so costly and have many performance problems. Methods: In this study, biodegradation of Amoxicillin by submerged biological aerated filter (SBAF) was evaluated in the aquatic environment. In order to assess the removal of Amoxicillin from the aquatic environment, this bioreactor was fed with synthetic wastewater based on sucrose and Amoxicillin at 3 concentration levels and 4 hydraulic retention times (HRTs). Results: The maximum efficiency for Amoxicillin and Soluble Chemical Oxygen Demand (SCOD) removal was 50.8% and 45.3%, respectively. The study findings showed that Stover- Kincannon model had very good fitness in loading Amoxicillin in the biofilter (R2 > 9 9%). T here w as n o a ccumulation o f Amoxicillin in the biofilm and the loss of Amoxicillin in the control reactor was negligible. This shows that removal of Amoxicillin from the system was due to biodegradation. Conclusions: It can be concluded that there was no significant inhibition effect on mixed aerobic microbial consortia. It was also observed that Amoxicillin degradation was dependent on the amount of Amoxicillin in the influent and by increasing the initial Amoxicillin concentration, Amoxicillin biodegradation increased, as well.
