Document Type : Original Article

Authors

1 Environmental Engineering, Islamic Azad University Science and Research Branch of Ahvaz, Ahvaz, Iran

2 Environmental Technologies Research Center, Faculty of Health, Avhaz Jundishapur University of Medical Science, Ahvaz, Iran

3 Department of Environmental Engineering, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran

Abstract

Background: Nowadays, the discharge of effluents containing chemicals through manufacturers or consumer industries causes major environmental problems. In this study, we assessed the effect of sludge reversal of the clarifier unit on enhancing the coagulant performance of Poly-Aluminum chloride in the removal of turbidity/COD/PVC from PVC effluent of Bandar Imam Khomeini petrochemical plant and reduction of the amount of coagulant and costs.
 
Methods: The experiments were carried out by Jar test with poly aluminum chloride (PAC); the returned sludge, as the assisting coagulant, and the amplitude of the differentiates including (5.5-11) pH of coagulant concentration (10-140mg/L) and concentration of returned sludge (2-20 ml) were investigated. To ensure the accuracy and precision, we repeated each stage of the experiment three times.
 
Results: The results showed that the most optimal conditions for coagulant were at pH=8 and the optimum dose of poly aluminum chloride was 25 mg/L plus 5ml of the clear sludge volume in the clarifier. The removal efficiency of turbidity, COD, and PVC under optimum conditions of Poly-Aluminum chloride were reported 99.71%, 97.19%, and 99.55%, respectively.
 
Conclusion: The results indicated that the sludge of the clarifier, as the main assisting coagulant,  in addition to increasing the efficiency of  the removal turbidity of COD and PVC reduced the dose of the main coagulant.

Keywords

1-Abbaspour M, Javid AH, Jalilzadeh Yengjeh R, Hassani AH, Mostafavi PG. The biodegradation of methyl tert-butyl ether (MTBE) by indigenous Bacillus cereus strain RJ1 isolated from soil. Petroleum Science and Technology. 2013;31(18):1835-41.
2-Lotfinejad A, Ghanavati B, Rahimi A. Investigating the coagulant used in the PVC unit Wastewater treatment process and determining its optimal Conditions. 1th National Conference on Health Safety and Enviroment (HSE), Mahshahr. Iran.2011.
3-Heidari L, Jalili Ghazizade M. Industrial waste management in PVC production process by focusing on caustic flake waste (Case study: Ghadeer Petrochemical Company, Mahshahr, Iran). In International Conference on Industrial Waste and Wastewater Treatment and Valorization, Athens 2015.
4-AlMubaddal F, AlRumaihi K, Ajbar A. Performance optimization of coagulation/flocculation in the treatment of wastewater from a polyvinyl chloride plant. Journal of hazardous materials. 2009 Jan 15;161(1):431-8.
5-Orooji N, Takdastan A, Kargari A, Raeesi G. Efficiency of chitosan with polyaluminum chloride in turbidity removal from Ahwaz water treatment plant influent. J Water Wastewater. 2012 Dec 1;35:70-.
6-Armin H, Omidi khaniabadi Y, Shams Khorramabadi Gh, Godini H, Takdastan A. Performance of clarifier recycled sludge as Coagulant aid to poly-feric sulfate in terms of removal efficiency of turbidity and total colifor from the river of Bahmanshir Abadan. Iran Journal of Health System Research, 2016;12(2).
7-Rahman MM, Sarker P, Saha B, Jakarin N, Shammi M, Uddin MK, Sikder MT. Removal of turbidity from the river water using tamarindus indica and litchi chinensis seeds as natural coagulant. International Journal of Environmental Protection and Policy. 2015 Feb 14;3(1-2):19-26.
8-Adams FV, Mulaba-Bafubiandi AF. Application of rice hull ash for turbidity removal from water. Physics and Chemistry of the Earth, Parts A/B/C. 2014 Jan 1;72:73-6.
9-Seid-Mohammadi A, Asgari G, Mobarakian SA, Taherkhani F. Removal of turbidity in raw water using chitosan in electrocoagulation process using aluminum electrodes. Journal of Gorgan University of Medical Sciences. 2016;17(4).
10-Hasheminejad H, Taebi Harandi A, Paydary P. Evaluation of Tannic Acid as Coagulant for Water Turbidity Reduction in Preliminary Water Treatment. JWSS-Isfahan University of Technology. 2018 Sep 10;22(2):189-98.
11-Takdastan A, Shrzadi SH, Orooji N, Noori-seoehr M, Jalilzadeh R. Evaluation and comparison of the efficiency of polymeric sulfate coagulant (PFS) in comparison with polyaluminum chloride (PAC) in removing turbidity and coliform in Ahvaz water treatment. Journal of Alborz University of Medical Sciences.2016;4(4): 266-277.
12-Farsani MH, Yengejeh RJ, Mirzahosseini AH, Monavari M, Mengelizadeh N. Effective leachate treatment by a pilot-scale submerged electro-membrane bioreactor. Environmental Science and Pollution Research. 2021:1-4.
13-Nikpour B, Yengejeh RJ, Takdastan A, Hassani AH, Zazouli MA. The investigation of biological removal of nitrogen and phosphorous from domestic wastewater by inserting anaerobic/anoxic holding tank in the return sludge line of MLE-OSA modified system. Journal of Environmental Health Science and Engineering. 2020:1-0.
14-Derakhshan-Nejad A, Rangkooy HA, Cheraghi M, Yengejeh RJ. Removal of ethyl benzene vapor pollutant from the air using TiO 2 nanoparticles immobilized on the ZSM-5 zeolite under UVradiation in lab scale. Journal of Environmental Health Science and Engineering. 2020 ;18(1):201-9.
15-Kazemi Noredinvand B, Takdastan A, Jalilzadeh Yengejeh R. Removal of organic matter from drinking water by single and dual media filtration: a comparative pilot study. Desalination and Water Treatment. 2016;57(44):20792-9.
16-Standard Method for the Examination of water and wastewater. 21st ed. American Public Association. Washington. DC. 2005.
17-Babaei AA, Ghanbari F, Yengejeh RJ. Simultaneous use of iron and copper anodes in photoelectro-Fenton process: concurrent removals of dye and cadmium. Water Science and Technology. 2017;75(7):1732-42.
18-Hesami F, Bina B, Ebrahimi A. The effectiveness of chitosan as coagulant aid in turbidity removal from water. International Journal of Environmental Health Engineering. 2014 Jan 1;3(1):8.
19-Mirzaei A, Takdastan A, Alavi Bakhtiar VN. Survey of PAC Performance for Removal of Turbidity COD Coliform Bacteria HeterotropHic Bacteria from water of Karoon River. Iran J Health and environment. 2011; 4(3):267-275.
20-Gyawali G, Rajbhandari A. Investigation on coagulation efficiency of polyaluminium silicate chloride (PASiC) coagulant. Scientific World. 2012 Sep 20;10(10):33-7.
21-Chirkut Likhar M, Vinayakrao shivramwar M.Removal of Chemical oxygen damand (COD) and color from dye manufacturing industry by coagulation. International Journal of Engineering Research and Applications. 2013;3(2),1116-1118.
22-Mirzaiy A, Takdastan A, Alavi N, Mohamadian H. Removal of turbidity, organic matter, coliform and heterotrophic bacteria by coagulants poly aluminium chloride from Karoon river water in Iran. Asian Journal of Chemistry. 2012 Jun 1;24(6):2389.
23-Farajnezhad H, Gharbani P. Coagulation treatment of wastewater in petroleum industry using poly aluminum chloride and ferric chloride. International Journal of Research and Reviews in Applied Sciences. 2012 Oct;13(1):306-10.
24-Pang FM, Teng SP, Teng TT, Omar AM. Heavy metals removal by hydroxide precipitation and coagulation-flocculation methods from aqueous solutions. Water Quality Research Journal. 2009 May;44(2):174-82.
25-Hu C, You L, Liu H, Qu J. Effective treatment of cadmium–cyanide complex by a reagent with combined function of oxidation and coagulation. Chemical Engineering Journal. 2015 Feb 15;262:96-100.
26-Tarzjani Dehghan M, Takdastan A, Eizanlo H, Kashfi H, kor Y. Survey of effect on clarifier sludge recycling by polyaluminum chloride (PAC) coagulant for improve the removal turbidity in Minab water Treatment plant. 1st National Conference on water and waste water Science and Technology,Ahvaz. Ran. 2011.
27-Kashfi H, Icor Y, Amirkhanlo B, Marganpour A. Effects of Sludge Recycling on Poly Aluminum Chloride Coagulant for Turbidity Total Coliform and Soli Protection in Minab Water treatment plant. 2th international Conference on Health Enviromental and sustainable development. BandarAbbas, Iran .2012.
28-Takdastan A, Neisi A, Jolanejad M, Ahmadi Angaly K, Abtahi M, Ahmadi MJ. The efficiency of coagulation process using polyaluminum silicate chloride (pasic) in removal of hexavalent chromium and cadmium from aqueous solutions. Journal of Mazandaran University of Medical Sciences. 2016 May 10;26(136):99-108.
29-Jamali HA, Ghahramani E, Abouee E, Sadeghi S. Evaluation of poly aluminium chloride efficiency in removal COD, TSS, color and turbidity of wastes landfill leachate in Qazvin city in 2011. Journal of north Khorasan university of medical sciences. 2014 Dec 10;6(3):581-9.